MATERIAL SAFETY DATA SHEET SAVAGE庐 DRY SOLUBLE HERBICIDE
FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC - DAY OR NIGHT 1-800-424-9300
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FORMULATED FOR:
Loveland Products, Inc. 24-Hour Emergency Phone: 1-800-424-9300
P.O. Box 1286 鈥? Greeley, CO 80632-1286 Medical Emergencies: 1-800-301-7976
PRODUCT NAME: SAVAGE庐 DRY SOLUBLE HERBICIDE
CHEMICAL NAME: 2,4-D; Dimethylamine salt of 2,4-dichlorophenoxyacetic acid
CHEMICAL FAMILY: Phenoxy Herbicide
EPA REG. NO.: 34704-606
MSDS Number: 000606-04-LPI MSDS Revisions: New Date Of Issue: 02/25/04 Supersedes: New
2. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Ingredients: Percentage by Weight: CAS No. TLV (Units)
10 mg/m3
Dimethylamine salt of 2,4-D 95.00 2008-39-1
2,4-D Acid (CAS: 94-75-7)
Dimethylamine (CAS: 124-40-3)
Inert Ingredients 5.00
3. HAZARDS IDENTIFICATION SUMMARY
KEEP OUT OF REACH OF CHILDREN 鈥? DANGER 鈥? PELIGRO 鈥? Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted
en detaile (If you do not understand the label, find someone to explain it to you in detail.) Corrosive. Causes irreversible eye damage. Do not get in
eyes or on clothing. Harmful if swallowed, inhaled, or absorbed through skin. Avoid contact with skin. Prolonged or frequently repeated skin contact may
cause allergic reactions in some individuals. Avoid breathing spray mist. Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse.
This product is off-white to tan-colored crystalline solid with 鈥渇ishy鈥? amine-like odor. Primary routes of entry are Inhalation, eye contact and skin contact.
4. FIRST AID MEASURES
If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
If swallowed: Call a poison control center or doctor immediately for treatment advice. Have a person sip a glass of water if able to do so. Do
not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an
unconscious person.
If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center
or doctor for treatment advice.
If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by
mouth-to-mouth, if possible. Call a poison control center or doctor for further treatment advice.
If in eyes, specialized ophthalmologic attention may be necessary. If swallowed, probable mucosal damage may
NOTE TO PHYSICIAN:
contraindicate gastric lavage. There is no specific antidote; treat symptomatically.
FOR A MEDICAL EMERGENCY INVOLVING THIS PRODUCT CALL: 1-800-301-7976. Have the product label or container with you when calling a poison control
center or doctor, or going for treatment.
5. FIRE FIGHTING MEASURES
FLASH POINT (掳F/Test Method): Not applicable
FLAMMABLE LIMITS (LEL & UEL): Not established
EXTINGUISHING MEDIA: Considered non-combustible, use medium appropriate to surrounding fire. Dry chemical, carbon
dioxide, foam, water spray or fog.
HAZARDOUS COMBUSTION PRODUCTS: May include but are not limited to ammonia, oxides of nitrogen, chlorine-containing compounds and
other unknown hazardous materials may be formed in a fire situation. Incomplete combustion may lead
to formation of oxides of carbon.
SPECIAL FIRE FIGHTING PROCEDURES: Smoke and fumes from fire may contain hazardous components. Wear self-contained breathing
apparatus and full protective gear. Fight fire from upwind and keep all non-essential personnel out of
area of intense smoke.
UNUSUAL FIRE AND EXPLOSION HAZARDS: If water is used to fight fire, contain run-off, using dikes to prevent contamination of water supplies.
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Avoid breathing dusts. Contain spill and sweep up material and transfer to containers for possible land application according to label use or for proper
disposal. Wash spill area with water containing strong detergent, absorb and sweep up as above. Check local, state and federal regulations for proper
disposal.
CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water.
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MATERIAL SAFETY DATA SHEET SAVAGE庐 DRY SOLUBLE HERBICIDE
7. HANDLING AND STORAGE
HANDLING: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide
gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the
outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing.
STORAGE: Store in a safe manner. Store in original container only. Store in a cool. dry place. Do not contaminate water, food or feed by
storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: When handlers use closed systems, enclosed cabs, or aircraft in a manner that meets with requirements listed in the
Worker Protection Standard (WPS) for agricultural pesticides [40 CFR 170.240(d)(4-6)], the handler PPE
requirements may be reduced or modified as specified in the WPS.
RESPIRATORY PROTECTION: Not normally required, if vapors or dusts exceed acceptable levels, wear a MSHA/NIOSH approved pesticide
respirator.
EYE PROTECTION: Chemical goggles or shielded safety glasses.
SKIN PROTECTION: Wear protective clothing: long-sleeved shirts and pants, shoes with socks. Wear rubber or chemical-resistant gloves.
OSHA PEL 8 hr TWA ACGIH TLV-TWA
10 mg/m3 10 mg/m3
2,4-D Acid
Personal Protective Equipment: Applicators and other handlers must wear: long sleeved shirt and long pants, chemical-resistant gloves, such as
barrier laminate, nitrile rubber, neoprene rubber or Viton庐, shoes plus socks, and protective eyewear. Follow manufacturer鈥檚 instructions for cleaning
and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. After each
day of use, clothing or PPE must no be reused until it has been cleaned.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR: Off-white to tan colored crystalline solid with 鈥渇ishy鈥? amine-like odor SOLUBILITY: Soluble
BULK DENSITY: 35 lbs/ft3
SPECIFIC GRAVITY (Water = 1): 0.561 g/ml pH: 9.0 (5% solution)
VAPOR PRESSURE: Not applicable BOILING POINT: Not applicable
PERCENT VOLATILE (by volume): Not applicable EVAPORATION RATE (Butyl Acetate = 1): <1
Note: These physical data are typical values based on material tested but may vary from sample to sample.
Typical values should not be construed as a guaranteed analysis of any specific lot or as specification items.
10. STABILITY AND REACTIVITY
STABILITY: Stable CONDITIONS TO AVOID: Excessive heat.
INCOMPATIBILITY: Strong acids and oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS: Ammonia, oxides of nitrogen, chlorine-containing compounds and other unknown hazardous materials
may be formed in a fire situation. Incomplete combustion may lead to formation of oxides of carbon.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Oral LD50 (rat): 1470 mg/kg Acute Dermal LD50 (rabbit): >2000 mg/kg
Eye Irritation (rabbit): Corrosive; causes irreversible eye damage Skin Irritation (rabbit): Not an irritant
Inhalation LC50 (rat): >5.46 mg/L (4 Hour) [male rat]. Skin Sensitization (guinea pig): Sensitizer
Carcinogenic Potential: None listed in OSHA, NTP, IARC or ACGIH
12. ECOLOGICAL INFORMATION
This product is toxic to aquatic invertebrates. Drift or runoff may adversely affect aquatic invertebrates and non-target plants. For terrestrial uses, do not
apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when
disposing of equipment wash water. Do not apply where runoff is likely to occur.
Do not apply when weather conditions favor drift from target area.
13. DISPOSAL CONSIDERATIONS
Do not reuse container. Paper Bag: completely empty bag into the application equipment. Then dispose of in a sanitary landfill or by incineration, or, if
allowed by State and local authorities, by burning. If burned, stay out of smoke. Plastic Bucket: Triple rinse (or equivalent) then offer for recycling at an
ACRC site or by reconditioning, or puncture and dispose in a sanitary landfill, or incineration, or, if allowed by State and local authorities, by burning. If
burned, stay out of smoke. Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law and
may contaminate groundwater. Do not contaminate water, food or feed by storage or disposal.
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MATERIAL SAFETY DATA SHEET SAVAGE庐 DRY SOLUBLE HERBICIDE
14. TRANSPORT INFORMATION
DOT Shipping Description: NOT REGULATED BY USDOT.
U.S. Surface Freight Classification: COMPOUND, TREE OR WEED KILLING, NOI (NMFC 50320, SUB 2: CLASS: 60)
Consult appropriate ICAO/IATA and IMDG regulations for shipment requirements in the Air and Maritime shipping modes
15. REGULATORY INFORMATION
NFPA & HMIS Hazard Ratings: NFPA HMIS
3 Health 0 Least 3 Health
0 Flammability 1 Slight 0 Flammability
0 Instability 2 Moderate 0 Reactivity
3 High H PPE
4 Severe
SARA Hazard Notification/Reporting
SARA Title III Hazard Category: Immediate __Y__ Fire __N__ Sudden Release of Pressure __N__
Delayed __Y__ Reactive __N__
Reportable Quantity (RQ) under U.S. CERCLA: 2,4-D Acid (CAS: 94-75-7) 100 pounds
SARA, Title III, Section 313: 2,4-D Acid (CAS: 94-75-7) 卤79.0%
RCRA Waste Code: Not listed
CA Proposition 65: Not listed
16. OTHER
MSDS STATUS: New
PREPARED BY: Registrations and Regulatory Affairs REVIEWED BY: Environmental/ Regulatory Services
庐Savage is a registered trademark
庐Viton is a registered trademark of DUPONT DOW ELASTOMERS L.L.C.
Although the information and recommendations set forth herein (hereinafter 鈥淚nformation鈥?) are presented in good faith and believed to be correct, Loveland
Products, Inc., the manufacturer or the seller makes no representations as to the completeness or accuracy thereof. Information is supplied upon the
condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to use.
The product covered by this information sheet is furnished 鈥渁s is鈥? by Loveland Products, Inc., the manufacturer or the seller, and is subject only to the
warranties, if any, that appear on the product鈥檚 label or are otherwise expressly provided herein.
Except as expressly provided on the product鈥檚 label or otherwise provided herein, no warranties, guarantees, or representations of any kind, either express
or implied, or by usage of trade, statutory or otherwise, are made by Loveland Products, Inc., the manufacturer or the seller with regard to the product or
use of the product, including, but not limited to, merchantability, fitness for a particular purpose, use or eligibility of the product for any particular trade
usage.
Except as expressly stated herein, Loveland Products, Inc., the manufacturer or the seller makes no warranty of results to be obtained by use of the
product covered by this information. Buyer鈥檚 or user鈥檚 exclusive remedy, and the total liability of Loveland Products, Inc., the manufacturer or the seller,
shall be limited to damages not exceeding the cost of the product. No agent or employee of Loveland Products, Inc., the manufacturer or the seller is
authorized to amend the terms of this warranty disclaimer or the product鈥檚 label or to make a representation or recommendation different from or
inconsistent with the label of this product.
IN NO EVENT SHALL LOVELAND PRODUCTS, INC., THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL OR
INDIRECT DAMAGES RESULTING FROM THE USE, HANDLING, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FOR
DAMAGES IN THE NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.
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